Carbon Disulfide → HCID 178433327, compound

HRID 1679955Notes

Reaction equation

HRID 1679955 reaction equation
[CH3:1][C:2]1[N:3]=[CH:4][NH:5][C:6]=1[CH2:7][S:8][CH2:9][CH2:10][NH2:11].[C:12](=[S:14])=[S:13]>C(O)C>[CH3:1][C:2]1[N:3]=[CH:4][NH:5][C:6]=1[CH2:7][S:8][CH2:9][CH2:10][NH:11][C:12](=[S:13])[SH:14]

Participants

4

Reactant 2

HCID 6348Carbon DisulfideHCID 178433288HCID 178433288, compound

Product 1

HCID 178433327HCID 178433327, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

(i) A solution of 4-methyl-5-((2-aminoethyl)thiomethyl)imidazole (10.2 g.) in ethanol (75 ml.) was added slowly, with stirring, to carbon disulphide (200 ml.). The mixture was set aside overnight at room temperature and the solid formed was collected and recrystallised from aqueous isopropyl alcohol to afford N-[2-((4-methyl-5-imidazolyl) methylthio)ethyl]dithiocarbamic acid (9.8 g.), m.p. 127°-129°.

Workup

  1. customthe solid formed
  2. customwas collected
  3. customrecrystallised from aqueous isopropyl alcohol

Sources & evidence

ORD record
ord-961c27c4f9724c098df41ed8434824fc
Source dataset
uspto-grants-1981_06
Patent number
US04271169

Reaction notes

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