Acetone → HCID 20497642, compound

HRID 1680317Notes

Reaction equation

HRID 1680317 reaction equation
[Cl:1][O-].[Na+].[CH:4]12[CH2:10][C:9](=[O:11])[CH:8]1CC=C2.[CH3:12][C:13]([CH3:15])=[O:14]>[OH-].[Na+].S(=O)(=O)(O)O>[Cl:1][CH:15]1[CH:13]([OH:14])[CH2:12][CH:10]2[CH:4]1[CH2:8][C:9]2=[O:11]

Participants

6

Reactant 3

HCID 180AcetoneHCID 297183Bicyclo[3.2.0]hept-2-en-6-oneHCID 23665760Sodium Hypochlorite

Product 1

HCID 20497642HCID 20497642, compound

Reagents, catalysts & solvents 2

HCID 1118Sulfuric AcidSolventHCID 14798Sodium HydroxideSolvent

Procedure

A mixture of 1 N sodium hypochlorite in 0.1 N sodium hydroxide (478 ml) and 2 N sulphuric acid (425 ml) was added to a solution of bicyclo[3,2,0]hept-2-ene-6-one (23.0 g) in acetone (500 ml). The resulting solution was stirred at room temperature for 24 hours.

Sources & evidence

ORD record
ord-27e758ac5eda4dd3b956eff0fbf461c0
Source dataset
uspto-grants-1981_06
Patent number
US04272629

Reaction notes

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