HRID1680673

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID31344

2,2-Dimethylpropane-1,3-diol

C5H12O2

HCID154269

1,4-Benzenedicarboxylic acid, ion(2-)

C8H4O4-2

HCID5461079

未命名化合物

结构：C1CCCCC1.CO.CO.O=C(O)c1ccc(C(=O)O)cc1

HCID19348892

未命名化合物

PRODUCTS

生成物

结构：O=C([O-])c1ccc(C(=O)[O-])c(C(=O)[O-])c1.O=C([O-])c1cccc(C(=O)[O-])c1

HCID23455597

未命名化合物

结构：O=C([O-])c1ccc(C(=O)[O-])c(C2CCCCC2)c1

HCID86737815

未命名化合物

PROCEDURE

实验过程

The terephthalate or isophthalate from Stage I is in the form of a neopentyl glycol or cyclohexane dimethanol terephthalic acid oligomer which is then reacted in in Stage II with trimellitic anhydride or acid to provide a neopentyl or cyclohexane-terephthalate or isophthalate-trimellitate. The mole ratio of the neopentyl or cyclohexane terephthalate or isophthlate to the trimellitic anhydride or acid is in the range of between about 2.5 and about 5.5.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-f5574c0bea45421f9895bc7f8e67ad09
来源数据集: uspto-grants-1981_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04275189
来源说明: uspto-grants-1981_06

反应 SMILES

[C:1]([O-:12])(=[O:11])[C:2]1[CH:10]=[CH:9][C:5]([C:6]([O-:8])=[O:7])=[CH:4][CH:3]=1.[C:13]([O-:24])(=[O:23])[C:14]1[CH:22]=[CH:21][CH:20]=[C:16]([C:17]([O-:19])=[O:18])[CH:15]=1.OCC(C)(CO)C.[C:32]([OH:43])(=[O:42])[C:33]1[CH:41]=[CH:40][C:36]([C:37]([OH:39])=[O:38])=[CH:35][CH:34]=1.CO.CO.C1CCCCC1>>[CH:14]1([C:9]2[C:5]([C:6]([O-:8])=[O:7])=[CH:4][CH:3]=[C:2]([C:1]([O-:12])=[O:11])[CH:10]=2)[CH2:22][CH2:21][CH2:20][CH2:16][CH2:15]1.[C:13]([O-:24])(=[O:23])[C:14]1[CH:22]=[CH:21][CH:20]=[C:16]([C:17]([O-:19])=[O:18])[CH:15]=1.[C:32]([O-:43])(=[O:42])[C:33]1[C:34](=[CH:35][C:36](=[CH:40][CH:41]=1)[C:37]([O-:39])=[O:38])[C:6]([O-:8])=[O:7]