HCID 20231523, compound → HCID 23455922, compound

HRID 1680728Notes

Reaction equation

NC(CCCCCCCCC(N)C(C)C)C(C)C.C(C1CC=CCCC=CCC(C(C)C)N=N1)(C)C.[CH3:37][CH2:38][CH2:39][CH:40]([CH:45]1[CH2:56][CH:55]=[CH:54][CH2:53][CH2:52][CH:51]=[CH:50][CH2:49][CH:48]([CH:57]([CH2:61][CH2:62][CH2:63][CH3:64])[CH2:58][CH2:59][CH3:60])[N:47]=[N:46]1)[CH2:41][CH2:42][CH2:43][CH3:44]>>[NH2:46][CH:45]([CH2:56][CH2:55][CH2:54][CH2:53][CH2:52][CH2:51][CH2:50][CH2:49][CH:48]([NH2:47])[CH:57]([CH2:58][CH2:59][CH3:60])[CH2:61][CH2:62][CH2:63][CH3:64])[CH:40]([CH2:39][CH2:38][CH3:37])[CH2:41][CH2:42][CH2:43][CH3:44]

Participants

Reactant 3

HCID 20231523HCID 20231523, compound

HCID 56635899HCID 56635899, compound

HCID 56639015HCID 56639015, compound

Product 1

HCID 23455922HCID 23455922, compound

Procedure

If there are used in the manner described under (a), instead of 250 g (1 mol) of 3,12-diisopropyl-1,2-diaza-1,5,9-cyclododecatriene, 35.9 g (0.09 mol) of crude 3,12-di-(4-octyl)-1,2-diaza-1,5,9-cyclododecatriene and correspondingly reduced amounts of catalyst and solvent, with otherwise the same procedure, there is obtained, after chromatographical purification and bulb-tube distillation, 8.8 g (24% of theory) of 6,15-diamino-5,16-dipropyleicosane in the form of colourless oil [nD20 =1.4655; IR (liquid) inter alia bands at 3380, 3300 and 1623 cm-1 ].

Workup

customwith otherwise the same procedure, there is obtained
distillationafter chromatographical purification and bulb-tube distillation, 8.8 g (24% of theory) of 6,15-diamino-5,16-dipropyleicosane in the form of colourless oil [nD20 =1.4655; IR (liquid) inter alia bands at 3380, 3300 and 1623 cm-1 ]

Sources & evidence

ORD record: ord-75641bd1711d470e81217c608626a728
Source dataset: uspto-grants-1981_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04275239

Reaction notes

Loading…