HuagongsheHuagongshe Chemistry Print Report · For research reference only
Aluminium lithium hydride → 2-(3,4-Methylenedioxyphenyl)ethyl 1-methycyclopropyl carbinol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Aluminium lithium hydride | HCID 21226445 | — |
| Reactant | 2-(3,4-Methylenedioxyphenyl)vinyl 1-methylcyclopropyl ketone | HCID 53712571 | — |
| Product | 2-(3,4-Methylenedioxyphenyl)ethyl 1-methycyclopropyl carbinol | HCID 23455738 | — |
Reaction Steps
2-(3,4-Methylenedioxyphenyl)ethyl 1-methylcyclopropyl carbinol [IV; Ar is 3,4-methylenedioxyphenyl, R is CH3 ] was prepared from 23.4 g. of 2-(3,4-methylenedioxyphenyl)vinyl 1-methylcyclopropyl ketone (Preparation A3) and 3.88 g. of lithium aluminum hydride according to the procedure described above in Preparation B1, affording 18.8 g., b.p. 120°-130° C. (0.003 mm.).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04275201 |
| Source dataset | uspto-grants-1981_06 |
| ORD ID | ord-0c391c1119a34da79f92a1ac8cf07be0 |
| Source note | uspto-grants-1981_06 |