Dimethyl Sulfoxide → HCID 23454834, compound

HRID 1680878Notes

Reaction equation

HRID 1680878 reaction equation
O.CO[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[C:10]([CH:12]=[O:13])=[O:11].[CH3:14][C:15]([NH2:26])([CH3:25])[CH2:16][C:17]1[CH:22]=[CH:21][C:20]([O:23][CH3:24])=[CH:19][CH:18]=1.[CH3:27]S(C)=O>>[CH3:25][C:15]([N:26]=[C:12]([O:13][CH3:27])[C:10]([C:5]1[CH:4]=[CH:9][CH:8]=[CH:7][CH:6]=1)=[O:11])([CH3:14])[CH2:16][C:17]1[CH:22]=[CH:21][C:20]([O:23][CH3:24])=[CH:19][CH:18]=1

Participants

4

Reactant 3

HCID 679Dimethyl Sulfoxide3×HCID 918922-(4-Methoxyphenyl)-1,1-dimethylethylamineHCID 204341102-Methoxyphenylglyoxal hydrate

Product 1

HCID 23454834HCID 23454834, compound

Conditions

Temperature
20 °C

Procedure

434 mg of 2-methoxyphenylglyoxal hydrate are dissolved in 0.5 ml of dimethylsulfoxide, and a solution of 427 mg of α,α-dimethyl-4-methoxyphenethylamine in 1.5 ml of dimethylsulfoxide is added thereto. The mixture is stirred at 20° C. for one hour, whereby a solution of α-(α,α-dimethyl-4-methoxyphenethylimino)-2-methoxyacetophenone in dimethylsulfoxide is obtained.

Sources & evidence

ORD record
ord-bfb0215f668248e8bf3f1e96b0b62971
Source dataset
uspto-grants-1981_06
Patent number
US04276304

Reaction notes

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