HCID 53665798, compound → HCID 13021464, compound

HRID 1680947Notes

Reaction equation

HRID 1680947 reaction equation
BrCC(=[O:11])CCC=C(C)CC.[Br:12][CH2:13][C:14](=[O:23])[CH2:15][CH2:16][CH:17]=[C:18]([CH3:22])[CH2:19][CH2:20][CH3:21].[Br:24][CH2:25][C:26](=[O:37])[CH2:27][CH2:28][CH:29]=[C:30]([CH3:36])[CH2:31][CH2:32][CH2:33][CH2:34][CH3:35]>>[Br:24][CH2:25][C:26](=[O:37])[CH2:27][CH2:28][CH:29]1[O:11][C:30]1([CH3:36])[CH2:31][CH2:32][CH2:33][CH2:34][CH3:35].[Br:12][CH2:13][C:14](=[O:23])[CH2:15][CH2:16][CH2:17][CH:18]([CH3:22])[CH2:19][CH2:20][CH3:21]

Participants

5

Reactant 3

HCID 53665798HCID 53665798, compoundHCID 54047845HCID 54047845, compoundHCID 54520197HCID 54520197, compound

Product 2

HCID 13021464HCID 13021464, compoundHCID 23454468HCID 23454468, compound

Procedure

When in the above procedure 1-bromo-6-methyl-2-oxo-oct-5-ene and 1-bromo-6-methyl-2-oxo-non-5-ene are employed in place of 1-bromo-6-methyl-2-oxo-undec-5-ene, the corresponding 1-bromo-5,6-epoxy-6-methyl-octan-2-one and 1-bromo-6-methyl-nonan-2-one are obtained.

Sources & evidence

ORD record
ord-009448ad24ec45088dced9d7ee46aa55
Source dataset
uspto-grants-1981_06
Patent number
US04276216

Reaction notes

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