HCID 10535817, compound → HCID 56996291, compound

HRID 1681005Notes

Reaction equation

HRID 1681005 reaction equation
[CH2:1]([O:8][C@H:9]([CH3:14])[CH2:10][C@H:11]([OH:13])[CH3:12])[C:2]1C=C[CH:5]=[CH:4][CH:3]=1.[I-].CCCCC>>[CH2:1]([O:8][C@H:9]([CH3:14])[CH2:10][C@H:11]([OH:13])[CH3:12])[CH2:2][CH2:3][CH2:4][CH3:5]

Participants

3

Reactant 2

HCID 10535817HCID 10535817, compoundHCID 18759699HCID 18759699, compound

Product 1

HCID 56996291HCID 56996291, compoundYield 42.3%

Procedure

2.90 g of the (2R, 4R)-4-benzyloxy-2-pentanol produced in Example 99 i) and 2.90 g of pentane iodide were subjected to the same procedure as in Example 99 i) to obtain 1.10 g of (2R, 4R)-4-pentyloxy-2-pentanol.

Sources & evidence

ORD record
ord-d51adc5b138146658e614b5b93db1d13
Source dataset
uspto-grants-1992_12
Patent number
US05167863

Reaction notes

Loading…