HCID 178443934, compound → HCID 178443931, compound

HRID 1681115Notes

Reaction equation

HRID 1681115 reaction equation
[CH3:1][C:2]1[C:6]([Cr:8][CH:9]=[C:10]([CH3:14])[CH:11]=[CH:12][CH3:13])([CH3:7])[C:5]([CH3:15])=[C:4]([CH3:16])[C:3]=1[CH3:17].[CH3:18]C(C=C(C)C)=C[K]>>[CH3:1][C:2]1[C:6]([Cr:8][CH:9]=[C:10]([CH3:14])[CH:11]=[C:12]([CH3:18])[CH3:13])([CH3:7])[C:5]([CH3:15])=[C:4]([CH3:16])[C:3]=1[CH3:17]

Participants

3

Reactant 2

HCID 178443934HCID 178443934, compoundHCID 178444642HCID 178444642, compound

Product 1

HCID 178443931HCID 178443931, compound

Procedure

The preparation of this compound was substantially the same as that described in Example 1 for [Cr(C5 (CH3)5)(C6H9)] except that 2, 4-dimethylpentadienyl potassium was used instead of 2-methyl pentadienyl lithium (as reported in H. Yashda, Y, Ohnuma, M. Yamauchi, H. Tani, and A. Nakamura, Bulletin Chem. Soc. Japan, 1979, 52, 2036).

Workup

  1. customThe preparation of this compound

Sources & evidence

ORD record
ord-a1c6103425954a339dc05dfc450ede2d
Source dataset
uspto-grants-1992_12
Patent number
US05169817

Reaction notes

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