Hexane → HCID 178477763, compound

Participants

Reaction Conditions

Reaction Steps

97.2 mg (0.372 mmol) of dichloromethylenebis(cyclopentadienyl)titanium was weighed out. Thereto 20 ml of dry toluene was added, and the mixture was cooled to a temperature of -78° C. 2.98 mmol of methylalumoxane (16-mer ) in toluene was added thereto dropwise with stirring, and the mixture was allowed to react at 50° C. for 6 hours. Then 20 ml of hexane was added to deposit a reddish brown solid. The solid was collected by filtration, recrystallized from toluene/hexane, and dried. The intended product was obtained in a yield of 71%.

Provenance & Evidence