化工社化工社 化学情報印刷レポート · 研究参考用
Water → Acetophenone
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Ethylbenzene | HCID 7500 | — |
| 反応物 | Sodium Sulfite | HCID 24437 | — |
| 反応物 | Lead nitrate | HCID 24924 | — |
| 生成物 | Acetophenone | HCID 7410 | 95% |
反応手順
Ten millimoles of ethylbenzene were heated at 400° C. for 1 hour with 1.35 ml of water containing 20 millimoles of sodium sulfite and 10 millimoles of lead nitrate. On cooling, a suspension of black precipitate was observed. The reaction product was extracted with ether and the ether layer was dried over Na2SO4 and concentrated to yield acetophenone in more than 95% yield. Acetophenone was confirmed by NMR and gas chromatographic techniques.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05171880 |
| 出典データセット | uspto-grants-1992_12 |
| ORD ID | ord-f2ef92410e4545f4b0b37e77be1d5962 |
| 出典メモ | uspto-grants-1992_12 |