Methyl methylphosphonochloridate → HCID 15037112, compound

HRID 1681518Notes

Reaction equation

CP(Cl)(=O)OC.[C:7]([O:10][CH:11]([C:27]1[CH:31]([OH:32])[O:30][C:29](=[O:33])[CH:28]=1)[CH2:12][O:13][C:14](=[O:26])[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])(=[O:9])[CH3:8]>>[C:7]([O:10][CH:11]([C:27]1[CH:31]([OH:32])[O:30][C:29](=[O:33])[CH:28]=1)[CH2:12][O:13][C:14](=[O:26])[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])(=[O:9])[CH2:8][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23]

Participants

Reactant 2

HCID 11499216Methyl methylphosphonochloridate

HCID 19019897HCID 19019897, compound

Product 1

HCID 15037112HCID 15037112, compound

Procedure

Using methyl methylphosphonochloridate in place of dodecanoyl chloride in the above-described procedure for making 4-(1-acetoxy-2-dodecanoyloxyethyl)-5-hydroxy-2(5H)-furanone, the product obtained is 4-[1-acetoxy-2-OP(0)(CCH3)(CH3) ethyl]-5-hydroxy-2(5H)-furanone.

Workup

customthe product obtained

Sources & evidence

ORD record: ord-ae7ce84dbb6f4b5c80f746306c821351
Source dataset: uspto-grants-1992_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05171863

Reaction notes

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