Cyclohexene oxide → Cyclohexanol

HRID 1682167Notes

Reaction equation

HRID 1682167 reaction equation
[CH:1]1([O:7]O)[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[CH:9]12[O:15][CH:10]1[CH2:11][CH2:12][CH2:13][CH2:14]2>C1CCCCC1>[CH:1]1([OH:7])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[C:10]1(=[O:15])[CH2:11][CH2:12][CH2:13][CH2:14][CH2:9]1.[CH:1]12[O:7][CH:2]1[CH2:3][CH2:4][CH2:5][CH2:6]2.[CH:1]1[CH2:6][CH2:5][CH2:4][CH2:3][CH:2]=1

Participants

7

Reactant 2

HCID 9246Cyclohexene oxideHCID 69835Cyclohexyl hydroperoxide

Product 4

HCID 7966CyclohexanolHCID 7967CyclohexanoneHCID 8079CyclohexeneHCID 9246Cyclohexene oxide

Reagents, catalysts & solvents 1

HCID 8078CyclohexaneSolvent

Procedure

In step b), the cyclohexyl hydroperoxide-containing mixture from step a) and a cyclohexene oxide-containing epoxidation mixture which is produced in step c) and essentially comprises cyclohexanol, cyclohexanone, cyclohexene oxide, cyclohexene, cyclohexane and catalyst are jointly separated by distillation. The mixtures from step a) and step c) to be distilled are advantageously mixed before introduction into the column. On distillation, the following fractions are separated:

Workup

  1. additioncontaining epoxidation mixture which

Sources & evidence

ORD record
ord-81f61183149d46ec9310377195e73480
Source dataset
uspto-grants-1992_12
Patent number
US05175316

Reaction notes

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