3,3-Dichlorocaprolactam → N-Benzoyl-3,3-dichlorocaprolactam

HRID 1682381Notes

Reaction equation

HRID 1682381 reaction equation
[C:1]([N:9]1[CH2:15][CH2:14][CH2:13][CH:12]([Cl:16])[CH2:11][C:10]1=[O:17])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Cl:18]C1(Cl)CCCNC(=O)C1>>[C:1]([N:9]1[CH2:15][CH2:14][CH2:13][C:12]([Cl:18])([Cl:16])[CH2:11][C:10]1=[O:17])(=[O:8])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

3

Reactant 2

HCID 190438153,3-DichlorocaprolactamHCID 190438231-Benzoyl-4-chloroazepan-2-one

Product 1

HCID 19043813N-Benzoyl-3,3-dichlorocaprolactam

Procedure

Synthesized as for N-benzoyl-3-chlorocaprolactam (Example VI) using 3,3-dichlorocaprolactam (prepared from caprolactam according to J. Am. Chem. Soc. 1958, 80, 6238) in place of 3-chlorocaprolactam.

Sources & evidence

ORD record
ord-72fa3c1b55b84575875cc4f74ee804f7
Source dataset
uspto-grants-1997_06
Patent number
US05635103

Reaction notes

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