HRID1683156

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CC(=O)OC[C@H]1O[C@@H](OCC[Si](C)(C)C)[C@H](N=[N+]=[N-])[C@@H](OC(C)=O)[C@H]1OC(C)=O

HCID53909159

未命名化合物

PRODUCTS

生成物

结构：C[Si](C)(C)CCO[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1N=[N+]=[N-]

HCID10859723

未命名化合物

收率 94%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID10942334

Methanol, sodium salt

CH3NaO

PROCEDURE

实验过程

Compound 23 (4.88 g, 11.3 mmol) was stirred in methanolic NaOMe (0.04M, 50 ml) for 90 min. The mixture was decationised with Amberlite IR-120(H+) resin, filtered and evaporated to dryness to give 24 (3.24 g, 94%), [α]D25 +8.5° (c 0.8, MeOH), m.p. 158°-161° C. (ether-heptane).

WORKUP

后处理

filtrationfiltered
customevaporated to dryness