4-Chloro-3-methylphenol → HCID 178444221, compound
Reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([OH:8])=[CH:4][C:3]=1[CH3:9].Br[CH2:11][CH:12]1[CH2:17][CH2:16][Si:15]([CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])(C2C=CC=CC=2)[CH2:14][CH2:13]1>>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([O:8][CH2:11][C@H:12]2[CH2:17][CH2:16][Si@H:15]([CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[CH2:14][CH2:13]2)=[CH:4][C:3]=1[CH3:9]Participants
3
Procedure
The general procedure of Example 9 was repeated using 4-chloro-3-methylphenol and 4-bromomethyl-1-n-heptyl-1-phenyl-1-silacyclohexane, thereby obtaining the intended compound.
Workup
- customobtaining the intended compound
Sources & evidence
- ORD record
- ord-2940b49c95504c968212e9e74be576e6
- Source dataset
- uspto-grants-1997_06
- Patent number
- US05641430
Reaction notes
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