4-Ethoxyphenol → HCID 178444520, compound
Reaction equation
[CH2:1]([O:3][C:4]1[CH:9]=[CH:8][C:7]([OH:10])=[CH:6][CH:5]=1)[CH3:2].Br[CH2:12][Si:13]1(C2C=CC=CC=2)[CH2:18][CH2:17][CH:16]([C@H:19]2[CH2:24][CH2:23][C@H:22]([CH2:25][CH2:26][CH2:27][CH:28]=[CH2:29])[CH2:21][CH2:20]2)[CH2:15][CH2:14]1>>[CH2:1]([O:3][C:4]1[CH:9]=[CH:8][C:7]([O:10][CH2:12][Si@H:13]2[CH2:14][CH2:15][C@H:16]([C@H:19]3[CH2:24][CH2:23][C@H:22]([CH2:25][CH2:26][CH2:27][CH:28]=[CH2:29])[CH2:21][CH2:20]3)[CH2:17][CH2:18]2)=[CH:6][CH:5]=1)[CH3:2]Participants
3
Procedure
The general procedure of Example 39 was repeated using 4-ethoxyphenol and trans-4-(4-bromomethyl-4-phenyl-4-silacyclohexyl)-1-(4-pentenyl)cyclohexane, thereby obtaining the intended product.
Workup
- customobtaining the intended product
Sources & evidence
- ORD record
- ord-d8b2f7efff3040d48e1301af21285edd
- Source dataset
- uspto-grants-1997_06
- Patent number
- US05641430
Reaction notes
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