HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbamide Peroxide → 4-Hydroxystyrene 7,8-oxide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbamide Peroxide | HCID 31294 | — |
| Reactant | 4-Vinylphenol | HCID 62453 | — |
| Reactant | alpha-L-xylo-2-Hexulofuranosonic acid, 2,3:4,6-bis-O-(1-methylethylidene)-, monohydrate | HCID 16211407 | — |
| Solvent | Tetrahydrofurane dichloromethane | HCID 21919333 | — |
| Product | 4-Hydroxystyrene 7,8-oxide | HCID 125089 | 66% |
Reaction Steps
Fifth recycle 4-Hydroxy styrene: 1 g, 8.3 mmol, urea hydrogen peroxide: 3 g, 32 mmol, Immobilized lipase: 87 mg, 2,3:4,6-di-O-isopropylidene-2-keto-L-gulonic acid monohydrate: 0.3 g, 1.03 mmol, dry dichloromethane:tetrahydrofuran (4:1): 15 mL. Same procedure was followed as described in example ‘1’. Reaction time: 20 hours, Yield: 66%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08148118B2 |
| Source dataset | uspto-grants-2012_04 |
| ORD ID | ord-b86ec42eca8e44ee86f800293e15d7e3 |
| Source note | uspto-grants-2012_04 |