Acetate → 5-[4-[2-[1-(Benzenesulfonyl)pyrrolidin-2-yl]ethenyl]-2-phenylmethoxyphenyl]-1,1-dioxo-2-(2-trimethylsilylethyl)-1,2,5-thiadiazolidin-3-one

HRID 168564Notes

Reaction equation

HRID 168564 reaction equation
[C:46]([P:47]([C:48]([CH3:49])([CH3:50])[CH3:51])[c:52]1[cH:53][cH:54][cH:55][cH:56][c:57]1-[c:58]1[cH:59][cH:60][cH:61][cH:62][cH:63]1)([CH3:64])([CH3:65])[CH3:66].[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][c:9]1[c:10]([N:16]2[CH2:17][C:18](=[O:29])[N:19]([CH2:23][CH2:24][Si:25]([CH3:26])([CH3:27])[CH3:28])[S:20]2(=[O:21])=[O:22])[cH:11][cH:12][c:13]([I:15])[cH:14]1.[CH3:67][C:68]#[N:69].[O-:71][C:72]([CH3:73])=[O:74].[O-:75][C:76]([CH3:77])=[O:78].[Pd+2:70].[c:30]1([S:36](=[O:37])(=[O:38])[N:39]2[CH:40]([CH:44]=[CH2:45])[CH2:41][CH2:42][CH2:43]2)[cH:31][cH:32][cH:33][cH:34][cH:35]1>>[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][c:9]1[c:10]([N:16]2[CH2:17][C:18](=[O:29])[N:19]([CH2:23][CH2:24][Si:25]([CH3:26])([CH3:27])[CH3:28])[S:20]2(=[O:21])=[O:22])[cH:11][cH:12][c:13]([CH:45]=[CH:44][CH:40]2[N:39]([S:36]([c:30]3[cH:31][cH:32][cH:33][cH:34][cH:35]3)(=[O:37])=[O:38])[CH2:43][CH2:42][CH2:41]2)[cH:14]1

Participants

7

Reactant 6

HCID 175Acetate2×HCID 6342AcetonitrileHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 27342152-(Di-tert-butylphosphino)biphenylHCID 667569375-(2-Benzyloxy-4-iodophenyl)-1,1-dioxo-2-(2-trimethylsilanylethyl)-1,2,5-thiadiazolidin-3-oneHCID 688399341-Benzenesulfonyl-2-vinylpyrrolidine

Product 1

HCID 688422705-[4-[2-[1-(Benzenesulfonyl)pyrrolidin-2-yl]ethenyl]-2-phenylmethoxyphenyl]-1,1-dioxo-2-(2-trimethylsilylethyl)-1,2,5-thiadiazolidin-3-one

Sources & evidence

ORD record
ord-55cde1acd0444bb2be9394c20085b772
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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