HCID 86632977, compound → HCID 57791935, compound

HRID 1686464Notes

Reaction equation

HRID 1686464 reaction equation
[F:1][C:2]1[CH:26]=[C:25]([S:27]([C:30]2[CH:35]=[CH:34][CH:33]=[CH:32][CH:31]=2)(=[O:29])=[O:28])[CH:24]=[CH:23][C:3]=1[O:4][C:5]1[CH:6]=[C:7]([CH2:19][C:20]([OH:22])=[O:21])[CH:8]=[C:9](OS(C(F)(F)F)(=O)=O)[CH:10]=1.[CH2:36]([Zn]CC)[CH3:37]>C1(C)C=CC=CC=1>[CH2:36]([C:9]1[CH:8]=[C:7]([CH2:19][C:20]([OH:22])=[O:21])[CH:6]=[C:5]([O:4][C:3]2[CH:23]=[CH:24][C:25]([S:27]([C:30]3[CH:35]=[CH:34][CH:33]=[CH:32][CH:31]=3)(=[O:29])=[O:28])=[CH:26][C:2]=2[F:1])[CH:10]=1)[CH3:37]

Participants

4

Reactant 2

HCID 86632977HCID 86632977, compoundHCID 178418750HCID 178418750, compound

Product 1

HCID 57791935HCID 57791935, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

The title compound was prepared as described in example 76 step (iii) but instead using the product of example 76 step (ii) and 2.0M diethylzinc in toluene.

Sources & evidence

ORD record
ord-58bafb968cd5407eadba04fcc0f03f16
Source dataset
uspto-grants-2012_04
Patent number
US08148572B2

Reaction notes

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