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HRID1687898

反应详情

EQUATION

反应方程式

HRID 1687898 的结构方程式

REACTANTS

反应物

2
结构：CC1(C)CCC(=O)Nc2ccc(N)cc21
HCID57853830

未命名化合物

结构：CC1(C)CCC(=O)Nc2cc([N+](=O)[O-])ccc21
HCID57853853

未命名化合物

PRODUCTS

生成物

1
结构：CC1(C)CCC(=O)Nc2cc(N)ccc21
HCID57416062

8-Amino-5,5-dimethyl-1,3,4,5-tetrahydro-2H-1-benzazepin-2-one

C12H16N2O

PROCEDURE

实验过程

8-Amino-5,5-dimethyl-1,3,4,5-tetrahydro-benzo[b]azepin-2-one was prepared in a manner analogous to the preparation of 7-Amino-5,5-dimethyl-1,3,4,5-tetrahydro-benzo[b]azepin-2-one by using 5,5-Dimethyl-8-nitro-1,3,4,5-tetrahydro-benzo[b]azepin-2-one as starting material (98%). LCMS: m/z=205.06 (M+H+), 1H NMR (400 MHz, CDCl3) δ 7.20 (d, 1H, J=8.3 Hz), 7.11 (bs, 1H), 6.51 (m, 1H), 6.24 (m, 1H), 3.74 (bs, 2H), 2.40 (m, 2H), 2.07 (m, 2H), 1.37 (s, 6H).