Nitric Acid → 1-Methyl-2-nitro-4-(pentafluoroethyl)benzene

HRID 1689724Notes

Reaction equation

HRID 1689724 reaction equation
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]([F:14])([F:13])[C:9]([F:12])([F:11])[F:10])=[CH:4][CH:3]=1.[N+:15]([O-])([OH:17])=[O:16]>>[CH3:1][C:2]1[CH:3]=[CH:4][C:5]([C:8]([F:13])([F:14])[C:9]([F:10])([F:11])[F:12])=[CH:6][C:7]=1[N+:15]([O-:17])=[O:16]

Participants

3

Reactant 2

HCID 944Nitric AcidHCID 141135221-Methyl-4-(pentafluoroethyl)benzene

Product 1

HCID 542079941-Methyl-2-nitro-4-(pentafluoroethyl)benzene

Procedure

Prepared from 1-methyl-4-(perfluoroethyl)benzene (1.95 g, 9.28 mmol) with sulfuric and nitric acid as described in EP 0418175 (1.45 g, 61%).

Sources & evidence

ORD record
ord-6addf5cc61244592b47006cd59721522
Source dataset
uspto-grants-2012_04
Patent number
US08153622B2

Reaction notes

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