HCID 178418389, compound → 1,1-Diamino-2,2-dinitroethylene

HRID 1694558Notes

Reaction equation

HRID 1694558 reaction equation
OC1C([N+]([O-])=O)([N+]([O-])=O)C(O)=[N:5][C:4](=[C:15]([N+:19]([O-:21])=[O:20])[N+:16]([O-:18])=[O:17])[N:3]=1.OC1C=C(O)N=C(C)N=1>>[NH2:3][C:4]([NH2:5])=[C:15]([N+:19]([O-:21])=[O:20])[N+:16]([O-:18])=[O:17]

Participants

3

Reactant 2

HCID 178418389HCID 178418389, compoundHCID 178526911HCID 178526911, compound

Product 1

HCID 5367701,1-Diamino-2,2-dinitroethyleneYield 85%

Procedure

The 4,6-dihydroxy-5,5-dinitro-2-(dinitromethylene)-2,5-dihydropyrimidine produced by the nitration reaction of 4,6-dihydroxy-2-methylpyrimidine in this example was hydrolyzed to give 1,1-diamino-2,2-dinitroethylene with the combined yield of 85%.

Sources & evidence

ORD record
ord-e7418d0fd7fc40ef8d3eaa8b69d96f94
Source dataset
uspto-grants-2012_04
Patent number
US08158788B2

Reaction notes

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