huagongshe.com
HRID1695594

反应详情

EQUATION

反应方程式

HRID 1695594 的结构方程式

REACTANTS

反应物

2
结构：COc1cccc2c1C(N)CCC2
HCID22147356

8-Methoxy-1,2,3,4-tetrahydronaphthalen-1-amine

C11H15NO

结构：CC(C)(C)[Si](C)(C)OCc1cc([N+](=O)[O-])ccc1N=C=S
HCID46855450

未命名化合物

PRODUCTS

生成物

1
结构：COc1cccc2c1C(NC1=Nc3ccc([N+](=O)[O-])cc3CO1)CCC2
HCID178488351

未命名化合物

收率 79.2%

PROCEDURE

实验过程

Prepared from tert-butyl-(2-isothiocyanato-5-nitro-benzyloxy)-dimethyl-silane (Example C1) (2.76 g, 8.5 mmol; HPLC: 4.446 min) and rac-8-methoxy-1,2,3,4-tetrahydro-naphthalen-1-ylamine (CAS 535935-61-6) (1.51 g, 8.5 mmol; HPLC 0.403 min) according to the procedure described for Example 1. Obtained the title compound as a yellow solid (2.38 g, 79%, HPLC 1.805 min), MS (ISP) m/e=354.2 [(M+H)+].