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HRID1696941

反应详情

EQUATION

反应方程式

HRID 1696941 的结构方程式

REACTANTS

反应物

3
反应SMILES：CC(C)(C)P(c1ccccc1-c1ccccc1)C(C)(C)C
HCID2734215

2-(Di-tert-butylphosphino)biphenyl

C20H27P

反应SMILES：CCOC(=O)c1cn(CCC#N)c2nc(N3CCC3)c(Br)cc2c1=O
HCID67275613

未命名化合物

反应SMILES：N#C[Zn]C#N
HCID178514179

未命名化合物

PRODUCTS

产物

1
反应SMILES：CCOC(=O)c1cn(CCC#N)c2nc(N3CCC3)c(C#N)cc2c1=O
HCID67274868

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
反应SMILES：O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.[Pd].[Pd]
催化剂HCID9811564

Bis(dibenzylideneacetone)palladium

C51H42O3Pd2

反应SMILES：CC#N
溶剂HCID6342

Acetonitrile

C2H3N

PROCEDURE

实验过程

A solution of EXAMPLE 82A (0.50 g), dicyanozinc (0.29 g), 2-(di-tert-butylphosphino)biphenyl (0.15 g), and tris(dibenzylideneacetone)dipalladium(0) (0.11 g) in acetonitrile (20 mL) was refluxed for 1 hour then cooled and filtered; and the filtrate was diluted with water and filtered.

WORKUP

后处理

  1. temperaturethen cooled
  2. filtrationfiltered
  3. additionand the filtrate was diluted with water
  4. filtrationfiltered