2-Bromo-6-methoxy-1,3-benzothiazole → 5-(1,3-benzothiazol-2-yl)-N-methylpyridin-2-amine

Participants

Reaction Steps

2-Bromo-6-methoxy-1,3-benzothiazole (49 mg, 0.20 mmol) and (5-chloro-6-methoxypyridin-3-yl)boronic acid (45 mg, 0.24 mmol) were reacted according to the procedure used for the preparation of 2-(6-bromopyridin-3-yl)-6-methoxy-1,3-benzothiazole to give the title compound (0.2 mg). 1H NMR (CHLOROFORM-d: CD3OD) δ 8.51 (d, 1H) 8.03 (dd, 1H) 7.87 (d, 1H) 7.43 (d, 1H) 7.10 (dd, 1H) 4.08 (s, 3H) 3.88 (s, 3H); MS m/z (M+H) 291.

Provenance & Evidence