Acetone → HCID 18380106, compound

HRID 1699103Notes

Reaction equation

HRID 1699103 reaction equation
[SH:1][CH2:2][C:3]([CH2:5][SH:6])=[CH2:4].[CH3:7][C:8]([CH3:10])=O.[Cl-].[Al+3].[Cl-].[Cl-].O>ClCCl>[CH3:7][C:8]1([CH3:10])[S:6][CH2:5][C:3](=[CH2:4])[CH2:2][S:1]1

Participants

6

Reactant 4

HCID 180AcetoneHCID 962WaterHCID 6451240Aluminum(III) ChlorideHCID 15271515HCID 15271515, compound

Product 1

HCID 18380106HCID 18380106, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

2-(Mercaptomethyl)-3-mercapto-1-propene (Z Chem. 1975, 15, 302)(0.83 g, 6.9 mmoles) and acetone (0.51 mL) were placed in about 15 mL of dichloromethane. Then anhydrous aluminium chloride (0.32 g) was added portionwise over one minute at room temperature. The solution was stirred at room temperature for 30 minutes. The reaction was worked up by addition of 20 mL of water followed by extraction with dichloromethane. The extracts were dried and evaporated to give 0.89 g clear oil with a penetrating smell. The oil was chromatographed to give 400 mg (40%) of clear oil.

Workup

  1. extractionfollowed by extraction with dichloromethane
  2. customThe extracts were dried
  3. customevaporated

Sources & evidence

ORD record
ord-ca925fd4133f448e814f72d09745394f
Source dataset
uspto-grants-2002_02
Patent number
US06344556B1

Reaction notes

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