HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1699884Generated: November 1, 2026
N-bromobutanimide → Methyl 4-(bromomethyl)-3-nitrobenzoate
https://huagongshe.com/reaction/1699884
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | Methyl 4-methyl-3-nitrobenzoate | HCID 81816 | — |
| Catalyst | Azobisisobutyronitrile | HCID 6547 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | Methyl 4-(bromomethyl)-3-nitrobenzoate | HCID 13399987 | 127.1% |
Reaction Steps
A mixture of methyl 3-nitro-4-methylbenzoate (4.147 g), N-bromosuccinimide (7.12 g) and AIBN (0.40 g) in carbon tetrachloride (30 ml) was stirred at 70° C. for 42 hr. After cooling, the insoluble matter was filtered off and the filtrate was concentrated to give an oil (7.40 g) containing the object compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06348474B1 |
|---|
| Source dataset | uspto-grants-2002_02 |
|---|
| ORD ID | ord-3396e68b5ce84a21b59a538a16606cb5 |
|---|
| Source note | uspto-grants-2002_02 |
|---|
