Chloroform → (S)-alpha-Methylstyrene oxide

HRID 1699985Notes

Reaction equation

HRID 1699985 reaction equation
[C@@H:1]12[O:11][C@@H:2]1CC[C:5]1[C:10]2=[CH:9][CH:8]=[CH:7][CH:6]=1.[CH:12](Cl)(Cl)Cl>>[CH3:12][C@@:1]1([C:10]2[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=2)[O:11][CH2:2]1

Participants

3

Reactant 2

HCID 6212ChloroformHCID 111161931807938-02-8

Product 1

HCID 11629614(S)-alpha-Methylstyrene oxide

Procedure

(1S,2R)-3,4-Dihydronaphthalene oxide (Table 6, entry 5) Colorless oil, [α]25D=−38.8° (c 0.91, CHCl3).

Sources & evidence

ORD record
ord-a023ea3e5da54f7d90ca45b065e48245
Source dataset
uspto-grants-2002_02
Patent number
US06348608B1

Reaction notes

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