HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1701110Generated: October 26, 2026
4-Chlorobenzotrichloride → 3,4-Dichlorophenyltrichloromethane
https://huagongshe.com/reaction/1701110
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 4-Chlorobenzotrichloride | HCID 21277 | — |
| Reactant | Sulfur dichloride | HCID 25353 | — |
| Catalyst | Iron chloride (FeCl3) | HCID 24380 | — |
| Product | 3,4-Dichlorophenyltrichloromethane | HCID 25608 | 51.4% |
Reaction Steps
A mixture of 57.5 g (250 mmol) of p-chlorobenzotrichloride, 1.5 g (9.2 mmol) of iron(III) chloride and 28 g (272 mmol) of sulphur dichloride was warmed to 80° C. for 3 hours. Thereafter, it was worked up in the manner indicated in Example 1. 34 g of 3,4-dichlorobenzotrichloride were thus obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US04191711 |
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| Source dataset | uspto-grants-1980_03 |
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| ORD ID | ord-8d0885b3be5147fdbd3f704b1cb056dd |
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| Source note | uspto-grants-1980_03 |
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