HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Methyl-3-tert.-butoxypropan-1-ol → 1-Bromo-3-tert-butoxy-2-methylpropane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Methyl-3-tert.-butoxypropan-1-ol | HCID 12536779 | — |
| Reactant | Bromine triphenylphosphine | HCID 44191054 | — |
| Product | 1-Bromo-3-tert-butoxy-2-methylpropane | HCID 12923290 | 35% |
Reaction Steps
Reaction of rac.-3-tert. butoxy-2-methyl-1-propanol with bromine-triphenylphosphine using the procedure of Example 28 gave rac.-3-tert. butoxy-2-methyl-1-bromopropane in 35% yield as a colorless liquid, b.p. 67°-77° C. (bath temperature) (9 mm Hg.).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04191842 |
| Source dataset | uspto-grants-1980_03 |
| ORD ID | ord-b09300400c234f3ea01375a8a01cdf55 |
| Source note | uspto-grants-1980_03 |