Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Nitrone | HCID 6350 | — |
| Reactant | Nitrobenzene | HCID 7416 | — |
| Reactant | N-{2-[(2,4-Dibromo-6-methylphenyl)diazenyl]-5-(diethylamino)phenyl}acetamide | HCID 12525525 | — |
| Catalyst | Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI) | HCID 24350 | — |
| Solvent | Triethylamine | HCID 8471 | — |
| Product | HCID 20347454 | HCID 20347454 | — |
Reaction Steps
A stirred mixture of 3-acetylamino-4-(2', 4'-dibromo-6'-methylphenylazo)-N,N-diethylaniline (4.8 parts), copper (I) iodide (2.0 parts), formaldoxime trimer (1.8 parts), triethylamine (1.5 parts), and nitrobenzene (100 parts) was heated to 90° C. for 11/2 hours when thin layer chromatography showed reaction to be complete. Isolation by the method of Example 3 gave 3-acetylamino-4-(2'-cyano-4'-bromo-6'-methylphenylazo)-N,N-diethylaniline, infra red spectrum identical with that of authentic material.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04192800 |
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| Source dataset | uspto-grants-1980_03 |
|---|
| ORD ID | ord-a616496d42a3440c8ed8749dd2594dfe |
|---|
| Source note | uspto-grants-1980_03 |
|---|
