HuagongsheHuagongshe Chemistry Print Report · For research reference only
Nerol → (Z)-1,1-Diethoxy-6,10-dimethyl-5,9-undecadien-2-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Nerol | HCID 643820 | — |
| Reactant | Neryl bromide | HCID 6087681 | — |
| Reactant | Ethyl 4,4-diethoxy-3-oxobutanoate | HCID 11138577 | — |
| Product | (Z)-1,1-Diethoxy-6,10-dimethyl-5,9-undecadien-2-one | HCID 13291922 | — |
Reaction Steps
Reaction of neryl bromide which had been prepared from 31 g of nerol with 41.5 g of ethyl 4,4-diethoxyacetoacetate was carried out in the same manner as in Referential example 1 to yield 20 g of the desired product, b.p. 122° C./0.02 mmHg.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04192953 |
| Source dataset | uspto-grants-1980_03 |
| ORD ID | ord-0e3c01fd41bd4fa8bd7e61e38ca9f992 |
| Source note | uspto-grants-1980_03 |