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HRID1701473

反应详情

EQUATION

反应方程式

HRID 1701473 的结构方程式

REACTANTS

反应物

3
结构：CC(=O)[O-]
HCID175

Acetate

C2H3O2-

结构：CC(=O)OC(C)=O
HCID7918

Acetic anhydride

C4H6O3

结构：C[C@]12CC[C@H](O)CC1CC[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@]12O
HCID53946591

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)O[C@H]1CC[C@@]2(C)C(CC[C@@H]3[C@@H]2CC[C@]2(C)C(=O)CC[C@]32O)C1
HCID70585703

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：c1ccncc1
溶剂HCID1049

Pyridine

C5H5N

PROCEDURE

实验过程

3β,14β-Dihydroxyandrostan-17-one (70 mg.) was dissolved in 5 ml. of pyridine and treated with 1 ml. of acetic anhydride at room temperature for 15 hours. After evaporation of solvents, the residue was crystallized from ether to give 70 mg. of the acetate, m.p. 182°-184°.

WORKUP

后处理

  1. customAfter evaporation of solvents
  2. customthe residue was crystallized from ether
  3. customto give 70 mg