HCID 15610185, compound → 12,21-Diaminodotriacontane

HRID 1701775Notes

Reaction equation

HRID 1701775 reaction equation
NC(CCCCCCCCC(N)CCC)CCC.C(C1CC=CCCC=CCC(CCC)N=N1)CC.[CH2:37]([CH:48]1[CH2:59][CH:58]=[CH:57][CH2:56][CH2:55][CH:54]=[CH:53][CH2:52][CH:51]([CH2:60][CH2:61][CH2:62][CH2:63][CH2:64][CH2:65][CH2:66][CH2:67][CH2:68][CH2:69][CH3:70])[N:50]=[N:49]1)[CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH3:47]>>[NH2:49][CH:48]([CH2:59][CH2:58][CH2:57][CH2:56][CH2:55][CH2:54][CH2:53][CH2:52][CH:51]([NH2:50])[CH2:60][CH2:61][CH2:62][CH2:63][CH2:64][CH2:65][CH2:66][CH2:67][CH2:68][CH2:69][CH3:70])[CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH3:47]

Participants

4

Reactant 3

HCID 15610185HCID 15610185, compoundHCID 56615476HCID 56615476, compoundHCID 570736363,12-Diundecyl-1,2-diaza-1,5,9-cyclododecatriene

Product 1

HCID 2055904312,21-DiaminodotriacontaneYield 64%

Procedure

If there are used in the manner described under (a), instead of 942 g (3.79 mols) of 3,12-dipropyl-1,2-diaza-1,5,9-cyclododecatriene, 100 g (0.21mol) of crude 3,12-diundecyl-1,2-diaza-1,5,9-cyclododecatriene (diastereoisomeric mixture) and correspondingly reduced amounts of catalyst and solvent, with the procedure otherwise being the same, there is obtained 64.3 g (64% of theory) of 12,21-diaminodotriacontane [m.p. 45°-46° C.; IR (CH2Cl2) inter alia bands at 3174 and 1582 cm-1 ].

Sources & evidence

ORD record
ord-ec296297bf824f578a571b6e61516a09
Source dataset
uspto-grants-1980_03
Patent number
US04195165

Reaction notes

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