HCID 15610185, compound → HCID 20231523, compound

HRID 1701776Notes

Reaction equation

HRID 1701776 reaction equation
NC(CCCCCCCCC(N)CCC)CCC.C(C1CC=CCCC=CCC(CCC)N=N1)CC.[CH:37]([CH:40]1[CH2:51][CH:50]=[CH:49][CH2:48][CH2:47][CH:46]=[CH:45][CH2:44][CH:43]([CH:52]([CH3:54])[CH3:53])[N:42]=[N:41]1)([CH3:39])[CH3:38]>>[NH2:41][CH:40]([CH2:51][CH2:50][CH2:49][CH2:48][CH2:47][CH2:46][CH2:45][CH2:44][CH:43]([NH2:42])[CH:52]([CH3:54])[CH3:53])[CH:37]([CH3:39])[CH3:38]

Participants

4

Reactant 3

HCID 15610185HCID 15610185, compoundHCID 56615476HCID 56615476, compoundHCID 56635899HCID 56635899, compound

Product 1

HCID 20231523HCID 20231523, compoundYield 92.8%

Procedure

If there are used in the manner described under (a), intead of 942 g (3.79 mols) of 3,12-dipropyl-1,2-diaza-1,5,9-cyclododecatriene, 250 g (1 mol) of 3,12-diisopropyl-1,2-diaza-1,5,9-cyclododecatriene (diastereoisomeric mixture) and correspondingly reduced amounts of catalyst and solvent, with the procedure otherwise being the same, there is obtained, as the main fraction, 238 g (92% of theory) of 3,12-diamino-2,13-dimethyltetradecane as colourless oil [b.p. 106°-109° C./0.01 Torr; nD20 =1.4600; IR (liquid) inter alia bands at 3355, 3278 and 1613 cm-1 ].

Sources & evidence

ORD record
ord-813ff1617eb541e5947ada529098926a
Source dataset
uspto-grants-1980_03
Patent number
US04195165

Reaction notes

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