HCID 15610185, compound → 3,14-Diethylhexadecane-4,13-diamine

HRID 1701777Notes

Reaction equation

HRID 1701777 reaction equation
[NH2:1][CH:2]([CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH:14]([NH2:18])[CH2:15][CH2:16][CH3:17])[CH2:3][CH2:4][CH3:5].[CH2:19](C1CC=CCCC=CCC(CCC)N=N1)[CH2:20]C.[CH3:37][CH2:38]C(N1CCCCCCCCC(C(CC)CC)NC1)CC>>[NH2:1][CH:2]([CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH:14]([NH2:18])[CH:15]([CH2:37][CH3:38])[CH2:16][CH3:17])[CH:3]([CH2:19][CH3:20])[CH2:4][CH3:5]

Participants

4

Reactant 3

HCID 15610185HCID 15610185, compoundHCID 20346523HCID 20346523, compoundHCID 56615476HCID 56615476, compound

Product 1

HCID 202315203,14-Diethylhexadecane-4,13-diamine

Procedure

If there are used in the manner described under (a), instead of 942 g (3.79 mols) of 3,12-dipropyl-1,2-diaza-1,5,9-cyclododecatriene, 49 g (0.159 mol) of 3,12-di-(3-pentyl)-1,3-diazacyclododecane and correspondingly reduced amounts of catalyst and solvent, there is obtained, after chromatographic purification and distillation, 26.8 g (54% of theory) of 4,13-diamino-3,14-diethylhexadecane as colourless oil [b.p. 141°-143° C./0.004 Torr; nD° =1.4666; IR (liquid) inter alia bands at 3378, 3278 and 1613 cm-1 ].

Workup

  1. customthere is obtained
  2. distillationafter chromatographic purification and distillation, 26.8 g (54% of theory) of 4,13-diamino-3,14-diethylhexadecane as colourless oil [b.p. 141°-143° C./0.004 Torr

Sources & evidence

ORD record
ord-f6869ab4493b4b268d930df678a59bfa
Source dataset
uspto-grants-1980_03
Patent number
US04195165

Reaction notes

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