HCID 15610185, compound → 6,15-Diamino-5,16-diethyleicosane

HRID 1701779Notes

Reaction equation

HRID 1701779 reaction equation
NC(CCCCCCCCC(N)CCC)CCC.C(C1CC=CCCC=CCC(CCC)N=N1)CC.[CH3:37][CH2:38][CH:39]([CH:44]1[CH2:55][CH2:54][CH2:53][CH2:52][CH2:51][CH2:50][CH2:49][CH2:48][CH:47]([CH:56]([CH2:59][CH2:60][CH2:61][CH3:62])[CH2:57][CH3:58])[NH:46][NH:45]1)[CH2:40][CH2:41][CH2:42][CH3:43]>>[NH2:45][CH:44]([CH2:55][CH2:54][CH2:53][CH2:52][CH2:51][CH2:50][CH2:49][CH2:48][CH:47]([NH2:46])[CH:56]([CH2:57][CH3:58])[CH2:59][CH2:60][CH2:61][CH3:62])[CH:39]([CH2:38][CH3:37])[CH2:40][CH2:41][CH2:42][CH3:43]

Participants

4

Reactant 3

HCID 15610185HCID 15610185, compoundHCID 23455925HCID 23455925, compoundHCID 56615476HCID 56615476, compound

Product 1

HCID 205590276,15-Diamino-5,16-diethyleicosane

Procedure

If there are used in the manner described under (a), instead of 942 g (3.79 mols) of 3,12-dipropyl-1,2-diaza-1,5,9-cyclododecatriene, 74.8 g (0.2 mol) of 3,12-di-(3-heptyl)-1,2-diazacyclododecane (diastereoisomeric mixture) and correspondingly reduced amounts of catalyst and solvent, using otherwise the same procedure, there is obtained, after chromatographic purification and distillation, 29.9 g (40% of theory) of 6,15-diamino-5,16-diethyleicosane as colourless oil [b.p. 170° C./0.01 Torr; nD20 =1.4662; IR (liquid) inter alia bands at 3278 and 1613 cm-1 ].

Workup

  1. customthere is obtained
  2. distillationafter chromatographic purification and distillation, 29.9 g (40% of theory) of 6,15-diamino-5,16-diethyleicosane as colourless oil [b.p. 170° C./0.01 Torr

Sources & evidence

ORD record
ord-a4a00bed940b48e096a69a1f3fdbb29a
Source dataset
uspto-grants-1980_03
Patent number
US04195165

Reaction notes

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