HCID 15610185, compound → HCID 20559014, compound

HRID 1701780Notes

Reaction equation

HRID 1701780 reaction equation
NC(CCCCCCCCC(N)CCC)CCC.C(C1CC=CCCC=CCC(CCC)N=N1)CC.[CH2:37]([CH:41]1[CH2:52][CH:51]=[CH:50][CH2:49][CH2:48][CH:47]=[CH:46][CH2:45][CH:44]([CH2:53][CH:54]([CH3:56])[CH3:55])[N:43]=[N:42]1)[CH:38]([CH3:40])[CH3:39]>>[NH2:42][CH:41]([CH2:52][CH2:51][CH2:50][CH2:49][CH2:48][CH2:47][CH2:46][CH2:45][CH:44]([NH2:43])[CH2:53][CH:54]([CH3:56])[CH3:55])[CH2:37][CH:38]([CH3:39])[CH3:40]

Participants

4

Reactant 3

HCID 15610185HCID 15610185, compoundHCID 56615476HCID 56615476, compoundHCID 56628203HCID 56628203, compound

Product 1

HCID 20559014HCID 20559014, compound

Procedure

If there are used in the manner described under (a), instead of 942 g (3.79 mols) of 3,12-dipropyl-1,2-diaza-1,5,9-cyclododecatriene, 400 g (1.45 mols) of 3,12-diisobutyl-1,2-diaza-1,5,9-cyclododecatriene (diastereoisomeric mixture) and correspondingly reduced amounts of catalyst and solvent, with otherwise the same procedure, there is obtained, as the main fraction, 261 g (63% of theory) of 4,13-diamino-2,15-dimethylhexadexane as colourless oil [b.p. 168°-172° C./0.4 Torr; nD20 =1.4561; IR (liquid) inter alia bands at 3289, 3205 and 1600 cm-1 ].

Workup

  1. customwith otherwise the same procedure, there is obtained, as the main fraction, 261 g (63% of theory) of 4,13-diamino-2,15-dimethylhexadexane as colourless oil [b.p. 168°-172° C./0.4 Torr; nD20 =1.4561; IR (liquid) inter alia bands at 3289, 3205 and 1600 cm-1 ]

Sources & evidence

ORD record
ord-f89029dc1acd4d69911df67b5ca0043f
Source dataset
uspto-grants-1980_03
Patent number
US04195165

Reaction notes

Loading…