HCID 15610185, compound → HCID 20286840, compound

HRID 1701783Notes

Reaction equation

NC(CCCCCCCCC(N)CCC)CCC.C(C1CC=CCCC=CCC(CCC)N=N1)CC.[CH:37]1([CH:45]2[CH2:56][CH2:55][CH2:54][CH2:53][CH2:52][CH2:51][CH2:50][CH2:49][CH:48]([CH:57]3[CH2:64][CH2:63][CH2:62][CH2:61][CH2:60][CH2:59][CH2:58]3)[NH:47][NH:46]2)[CH2:44][CH2:43][CH2:42][CH2:41][CH2:40][CH2:39][CH2:38]1>>[NH2:46][CH:45]([CH:37]1[CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44]1)[CH2:56][CH2:55][CH2:54][CH2:53][CH2:52][CH2:51][CH2:50][CH2:49][CH:48]([NH2:47])[CH:57]1[CH2:64][CH2:63][CH2:62][CH2:61][CH2:60][CH2:59][CH2:58]1

Participants

Reactant 3

HCID 15610185HCID 15610185, compound

HCID 20332297HCID 20332297, compound

HCID 56615476HCID 56615476, compound

Product 1

HCID 20286840HCID 20286840, compound

Procedure

If there are used in the manner described under (a), instead of 942 g (3.79 mols) of 3,12-dipropyl-1,2-diaza-1,5,9-cyclododecatriene, 65 g (0.168 mol) of 3,12-dicyclooctyl-1,2-diazacyclododecane and correspondingly reduced amounts of catalyst and solvent, with otherwise the same procedure, there is obtained, after chromatographic purification, 43.6 g (66% of theory) of 1,10-diamino-1,10-dicyclooctyldecane as colourless oil (nD20 =1.5050; IR (liquid) inter alia bands at 3333, 3278 and 1613 cm-1).

Workup

customwith otherwise the same procedure, there is obtained
customafter chromatographic purification, 43.6 g (66% of theory) of 1,10-diamino-1,10-dicyclooctyldecane as colourless oil (nD20 =1.5050; IR (liquid) inter alia bands at 3333, 3278 and 1613 cm-1)

Sources & evidence

ORD record: ord-19bb0d1d268c48cc9b5ae887a43a9e33
Source dataset: uspto-grants-1980_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04195165

Reaction notes

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