Ammonia → HCID 14770684, compound

HRID 1701842Notes

Reaction equation

HRID 1701842 reaction equation
[NH3:1].[C:2]([C:4]1[C:9]([Cl:10])=[CH:8][CH:7]=[CH:6][C:5]=1[S:11](Cl)(=[O:13])=[O:12])#[N:3]>O1CCOCC1.O>[NH2:3][C:2]1[C:4]2[C:9]([Cl:10])=[CH:8][CH:7]=[CH:6][C:5]=2[S:11](=[O:13])(=[O:12])[N:1]=1

Participants

5

Reactant 2

HCID 222AmmoniaHCID 189744283-Chloro-2-cyanobenzenesulfonyl chloride

Product 1

HCID 14770684HCID 14770684, compound

Reagents, catalysts & solvents 2

HCID 962WaterSolventHCID 312751,4-DioxaneSolvent

Procedure

12.5 ml of 25% ammonia were added at approx. 60° C. to a solution of 11,8 g of 2-cyano-3-chlorobenzenesulphonylchloride in 20 ml of dioxane. After heating on a steam bath for 30 minutes the reaction mixture was cooled and diluted with water. The resulting crystalline product was sucked off, washed with water and dried. The desired product was obtained in a yield of 8.9 g. After recrystallization from ethanol, the product melted at 261°-263° C.

Workup

  1. temperatureAfter heating on a steam bath for 30 minutes the reaction mixture
  2. temperaturewas cooled
  3. washwashed with water
  4. customdried

Sources & evidence

ORD record
ord-e99cfa74832c44fb815b02e4a5c3827b
Source dataset
uspto-grants-1983_04
Patent number
US04379157

Reaction notes

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