Water → HCID 13146585, compound

HRID 1701934Notes

Reaction equation

HRID 1701934 reaction equation
C([O:8][C:9]1[CH:14]=[CH:13][CH:12]=[C:11]([Si:15]([CH3:23])([CH3:22])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21])[CH:10]=1)C1C=CC=CC=1.O.[H][H]>[Pd].C(O)C>[CH3:22][Si:15]([CH3:23])([CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21])[C:11]1[CH:10]=[C:9]([OH:8])[CH:14]=[CH:13][CH:12]=1

Participants

6

Reactant 3

HCID 962WaterHCID 13146584HCID 13146584, compoundHCID 178418361HCID 178418361, compound2×

Product 1

HCID 13146585HCID 13146585, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

A mixture of 34.8 g. (0.107 mole) of 1-benzyloxy-3-(dimethyl-hexylsilyl)benzene, 2.0 g. of a 1:1 mixture by weight to volume of 5% by weight palladium on carbon and water, and 100 ml. ethanol was stirred under 1 atm. hydrogen at 25° C. until hydrogen uptake ceased (after an uptake of 2.5 liters). The reaction was filtered through Supercel with ethanol and the filtrate evaporated to a quantitative yield of the title compound as an oil.

Workup

  1. additionA mixture of 34.8 g
  2. filtrationThe reaction was filtered through Supercel with ethanol

Sources & evidence

ORD record
ord-9641178670dc45c2832ea6404c067f46
Source dataset
uspto-grants-1983_04
Patent number
US04379783

Reaction notes

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