HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl 4-chloroacetoacetate → HCID 12953392, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl 4-chloroacetoacetate | HCID 69484 | — |
| Reactant | Benzenecarbothioamide, 3-bromo- | HCID 2757186 | — |
| Product | HCID 12953392 | HCID 12953392 | 74.8% |
Reaction Steps
3-Bromothiobenzamide (10.8 g) and ethyl 4-chloroacetoacetate (8.3 g) were dissolved in 50 ml of alcohol. The reaction was stirred and heated under reflux for 4 hours. When cooled, the crystalline solid was filtered yielding 12.2 g of product, mp 65°-70° C. When recrystallized from ether-petroleum ether, it melted 68°-70° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04379791 |
| Source dataset | uspto-grants-1983_04 |
| ORD ID | ord-d69e381a0a3c4c05879b3d4f8ce391ff |
| Source note | uspto-grants-1983_04 |