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HRID1702004

反应详情

EQUATION

反应方程式

HRID 1702004 的结构方程式

REACTANTS

反应物

2
结构：Cc1ccc(S(=O)O)cc1
HCID10818

Benzenesulfinic acid, 4-methyl-

C7H8O2S

结构：CC(C)(C)C(=O)C=Cc1ccc(Cl)cc1
HCID306049

1-(4-Chlorophenyl)-4,4-dimethylpent-1-en-3-one

C13H15ClO

PRODUCTS

生成物

1
结构：Cc1ccc(S(=O)(=O)C(CC(=O)C(C)(C)C)c2ccc(Cl)cc2)cc1
HCID13178694

未命名化合物

收率 98.9%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCO
溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

A mixture of 3 g of 4-chlorobenzalpinacolone, 2 g of p-toluenesulfinic acid and 15 ml of ethanol was refluxed for 8 hours and then allowed to stand at a room temperature overnight. The collection of the precipitated crystals gave 4.8 g of the captioned compound (yield: 94%). m.p. 170°-171° C.

WORKUP

后处理

  1. temperaturewas refluxed for 8 hours
  2. customThe collection of the precipitated crystals