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HRID1702072

反应详情

EQUATION

反应方程式

HRID 1702072 的结构方程式

REACTANTS

反应物

1
结构：CON=C(C(=O)NC1C(=O)N2C(C(=O)O)C(O)CS[C@H]12)C1(CBr)OCCO1
HCID86738090

未命名化合物

PRODUCTS

生成物

1
结构：CON=C(C(=O)CBr)C(=O)NC1C(=O)N2C(C(=O)O)C(O)CS[C@H]12
HCID86738091

未命名化合物

收率 66.2%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CC(=O)O
溶剂HCID176

Acetic Acid

C2H4O2

PROCEDURE

实验过程

7-[2-Methoxyimino-3,3-ethylenedioxy-4-bromobutyramido]-3-hydroxycepham-4-carboxylic acid (syn isomer, 1 g.), 70% aqueous hydroperchloric acid (0.2 ml.) and acetic acid (2 ml.) were treated in a similar manner to that of Example 10 (4) to give 7-[2-methoxyimino-3-oxo-4-bromobutyramido]-3-hydroxycepham-4-carboxylic acid (syn isomer, 0.6 g.).