HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dicyclohexylamine → 6-(N,N-Di-cyclohexyl-amino)-dibenz[c,e][1,2]oxaphosphorine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dicyclohexylamine | HCID 7582 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | 6H-Dibenz[c,e][1,2]oxaphosphorin, 6-chloro- | HCID 89816 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 6-(N,N-Di-cyclohexyl-amino)-dibenz[c,e][1,2]oxaphosphorine | HCID 20504146 | — |
Reaction Steps
35.1 g (0.15 mol) of 6-chloro-dibenz[c,e][1,2]oxaphosphorine, 27.1 g (0.15 mol) of dicyclohexylamine and 50 ml of triethylamine are kept at reflux temperature for 10 hours. Toluene is added to the solution; the triethylamine hydrochloride is then removed by filtration, and the filtrate is concentrated in vacuo. The crystalline product has a melting point of 162° C. (Compound I).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04380515 |
| Source dataset | uspto-grants-1983_04 |
| ORD ID | ord-8997c1d832b343b2a7cb877c766f8f66 |
| Source note | uspto-grants-1983_04 |