Ammonia → Ammonia

HRID 1702224Notes

Reaction equation

HRID 1702224 reaction equation
[NH3:1].[Cu:2].[NH2:3][C:4]1[CH:5]=[C:6]([Cl:11])[CH:7]=[C:8]([NH2:10])[CH:9]=1>ClC1C=CC=CC=1>[NH2:3][C:4]1[CH:5]=[C:6]([NH2:1])[CH:7]=[C:8]([NH2:10])[CH:9]=1.[NH3:3].[NH2:3][C:4]1[CH:5]=[C:6]([Cl:11])[CH:7]=[C:8]([NH2:10])[CH:9]=1.[Cu:2]

Participants

8

Reactant 3

HCID 222Ammonia2×HCID 23978CopperHCID 733351,3-Benzenediamine, 5-chloro-

Product 4

HCID 222AmmoniaHCID 23978CopperHCID 669521,3,5-TriaminobenzeneHCID 733351,3-Benzenediamine, 5-chloro-

Reagents, catalysts & solvents 1

HCID 7964ChlorobenzeneSolvent

Procedure

An aminobenzene is produced by reacting a chlorobenzene with ammonia in the presence of a copper type catalyst, namely by reacting ammonia with 3,5-diaminochlorobenzene to produce 1,3,5-triaminobenzene at a temperature of 150° to 250° C. at a molar ratio of ammonia of 2 to 10 to 3,5-diaminochlorobenzene in the presence of a copper compound catalyst.

Sources & evidence

ORD record
ord-5d54230eedd143a6996778d59ee9c4a8
Source dataset
uspto-grants-1983_04
Patent number
US04380670

Reaction notes

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