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HRID1702248

反应详情

EQUATION

反应方程式

HRID 1702248 的结构方程式

REACTANTS

反应物

2
结构：CN(C)Cc1ccc(CSCCN)o1
HCID162203

5-((2-Aminoethyl)thiomethyl)-N,N-dimethyl-2-furanmethanamine

C10H18N2OS

结构：COC1=NS(=O)(=O)N=C1OC
HCID12230538

3,4-dimethoxy-1,2,5-thiadiazole 1,1-dioxide

C4H6N2O4S

PRODUCTS

生成物

1
结构：COC1=NS(=O)(=O)N=C1NCCSCc1ccc(CN(C)C)o1
HCID178494329

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CO
溶剂HCID887

Methanol

CH4O

3 次

PROCEDURE

实验过程

A solution of 2-[(5-dimethylaminomethyl-2-furylmethylthio]ethylamine (2.14 g; 10.0 mmoles) in 25 ml of dry methanol was added dropwise over 35 minutes to a well stirred suspension of 3,4-dimethoxy-1,2,5-thiadiazole 1,1-dioxide (1.78 g; 10.0 mmoles) in 180 ml of dry methanol that had been cooled to 1° in an ice-water bath. After 15 minutes at 0°, a methanol solution of the title compound is produced. A TLC [silica/CH2Cl2 :CH3OH (9:1)] gave Rf=0.48.

WORKUP

后处理

  1. temperaturehad been cooled to 1° in an ice-water bath