HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Chloroethyl chloroformate → 2-((1,1-Dimethylethoxy)methyl)oxirane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Chloroethyl chloroformate | HCID 12305 | — |
| Reactant | 2-Propanol, 1-chloro-3-(1,1-dimethylethoxy)- | HCID 10920889 | — |
| Reactant | HCID 20524944 | HCID 20524944 | — |
| Catalyst | Tetrabutylphosphonium bromide | HCID 76564 | — |
| Solvent | 1,2-Dichloroethane | HCID 11 | — |
| Product | 2-((1,1-Dimethylethoxy)methyl)oxirane | HCID 24314 | — |
Reaction Steps
Following the procedure of Example 14, 3-tert-butoxy-1-chloro-2-propyl 2-chloroethyl carbonate (from the reaction of 3-tert-butoxy-1-chloro-2-propanol with 2-chloroethyl chloroformate) is heated in the presence of tetrabutylphosphonium bromide to produce tert-butyl glycidyl ether and ethylene dichloride as the principal reaction products.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04349482 |
| Source dataset | uspto-grants-1982_09 |
| ORD ID | ord-3d60cc05519a46f88dbcf9299c6c5ae3 |
| Source note | uspto-grants-1982_09 |