HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Chloro-4-nitrobenzene → HCID 13078526, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Chloro-4-nitrobenzene | HCID 7474 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 4-(Methylthio)phenol | HCID 14086 | — |
| Solvent | Sulfolane | HCID 31347 | — |
| Product | HCID 13078526 | HCID 13078526 | 99.7% |
Reaction Conditions
| Temperature | 150 °C |
|---|
Reaction Steps
A mixture of 23.6 g (0.150 mole) of 4-nitrochlorobenzene, 23.1 g (0.165 mole) of 4-(methylthio)phenol, 22.8 g (0.165 mole) of anhydrous K2CO3 and 150 ml of sulfolane was heated at 150° C. for 6 hrs. The product was recovered (39.1 g, 99.7% yield) as described in Example 1 and recrystallized from ethanol, which gave purified 1-(methylthio)-4-(4-nitrophenoxy)benzene, mp 59°-61° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04349568 |
| Source dataset | uspto-grants-1982_09 |
| ORD ID | ord-89a130e271db428288a9decd9bc55142 |
| Source note | uspto-grants-1982_09 |